The paper reappraises the operational definition of elements, adopted in the late eighteenth century, by investigating both epistemic discontinuities and continuities within the broader epistemological and cultural context. The first part points out the radical disruption that the operational definition implied for most of science, which consisted in giving up explanation, the primary goal of natural philosophy, because the new elements had to be discovered. The operational turn in chemistry is then compared to several well-discussed “revolutions,” including the Kantian, relativistic, and quantum revolutions in physics, which similarly modified our understanding of fundamental concepts of natural philosophy, such as time, space, and causation, by relating them to human capacities.
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