Article ID: CBB139630567

Primary Documents. 25. The Catalytic Decomposition of Alkylidenehydrazines as a Method for the Preparation of Hydrocarbons (2015)

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The oxidation of primary hydrazines of the aliphatic and cyclic series, our studies have shown, yields the same products as oxidation of primary aromatic hydrazines. Just as in the last case, the identity of the oxidation products depends on the conditions under which the oxidation takes place. During oxidation in an alkaline medium, the hydrazine group is substituted by hydrogen; the reaction proceeds so smoothly that it can be used as a method for producing hydrocarbons. During oxidation in an acidic medium, the hydrazine group is replaced by the acid radical. This reaction is common to primary hydrazines of all classes: chlorobenzene is obtained from the oxidation of phenylhydrazine with copper sulfate in hydrochloric acid solution (Gattermann); under the same conditions, menthylhydrazine yields menthyl chloride and menthene, as the products of the decomposition of the first compound (Kizhner).

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Article David E. Lewis; Vladislav Suntsov (2015) Introduction to an English Translation (Abridged) of Kizhner's Pioneering Papers on Deoxygenation. Bulletin for the History of Chemistry (pp. 61-64). unapi

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Authors & Contributors
Lewis, David E.
Suntsov, Vladislav
Sztejnberg, Aleksander
Dolecki, M.
Firestone, David
Gordin, Michael D.
Journals
Bulletin for the History of Chemistry
Substantia: An International Journal of the History of Chemistry
Ambix: Journal of the Society for the History of Alchemy and Chemistry
Mitteilungen der Gesellschaft Deutscher Chemiker, Fachgruppe Geschichte der Chemie
Historical Records of Australian Science
Kwartalnik Historii Nauki i Techniki
Publishers
Princeton University
AOCS Press
Sächsische Akademie der Wissenschaften
Springer
Concepts
Chemistry
Organic chemistry
Translations
Primary literature (historical sources)
Biographies
Terminology and nomenclature
People
Kischner, Nikolai Matwejewitsch (Кижнер, Николай Матвеевич)
Beilstein, Friedrich Konrad
Brown, Herbert Charles
Bruner, Ludwik
Henseleit, Kurt
Ingold, Christopher
Time Periods
20th century, early
19th century
20th century
18th century
Places
Germany
Russia
Italy
Cracow (Poland)
Moscow (Russia)
Institutions
University of Sydney
Rossiiskaia Akademiia Nauk
Ecole supérieure de pharmacie de Paris
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