Restrepo, Guillermo (Author)
The periodic system of chemical elements was historically devised by assessing order and similarity relationships among the elements from their compounds, that is, using the accumulated results of chemical practice and knowledge. However, the current approach to the system is based on an ontology of isolated atoms where similarities, especially, are addressed through resemblances of electronic configurations. Here we show how the historical approach can be combined with computational tools for data analysis to build up the system based on the compounds reported by chemists. The approach produces well-known similarities of chemical elements when applied to binary compounds. The results come from the analysis of 4,700 binary compounds of 94 chemical elements, whose resemblances are quantified based on the elements they form compounds with and the proportions of those combinations. It is found that similarities do not always correspond to columns of the conventional periodic table and that besides robust similarities such as those of alkali metals, halogens and lanthanoids, there are other mixed similarities involving transition metals and actinoids, some of which were already known for a long time. These similarities are described. Finally, the advantages and disadvantages of the electronic and the compound approach to the system are discussed. It is concluded that the current data availability and computational facilities make possible to think of a periodic system closer to the chemical milieu of compounds, bringing chemistry back to the system.
...More
Article
Luis Moreno-Martínez;
Annette Lykknes;
(2019)
The Periodic System and the Nature of Science: The History of the Periodic System in Spanish and Norwegian Secondary School Textbooks
(/isis/citation/CBB104800390/)
Article
Alfio Zambon;
(2019)
Periodicity Trees in a Secondary Criterion of Periodic Classification: Its Implications for Science Teaching and Communication
(/isis/citation/CBB365718021/)
Book
Eric R. Scerri;
Elena Ghibaudi;
(2020)
What Is A Chemical Element? A Collection of Essays by Chemists, Philosophers, Historians, and Educators
(/isis/citation/CBB142422947/)
Article
Gisela Boeck;
(2019)
Julius Lothar (von) Meyer (1830-1895) and the Periodic System
(/isis/citation/CBB601476539/)
Article
Ann E. Robinson;
(2019)
Order From Confusion: International Chemical Standardization and the Elements, 1947-1990
(/isis/citation/CBB340408815/)
Book
Geoff Rayner-Canham;
(2020)
The Periodic Table: Past, Present, and Future
(/isis/citation/CBB994980863/)
Chapter
Carmen J. Giunta;
Vera V. Mainz;
Gregory S. Girolami;
(2021)
Editors’ Introduction
(/isis/citation/CBB126242747/)
Article
Isabel Malaquias;
João A. B. P. Oliveira;
(2019)
Shaping the Periodic Classification in Portugal through (text)books and charts
(/isis/citation/CBB919212623/)
Article
Gebrekidan Mebrahtu;
Mengesha Ayene Ejigu;
(2019)
Are History Aspects Related to the Periodic Table Considered in Ethiopian Secondary School Chemistry Textbooks?
(/isis/citation/CBB581572403/)
Article
Helge Kragh;
(2017)
On the Ontology of Superheavy Elements
(/isis/citation/CBB177176432/)
Chapter
Eric R. Scerri;
(2020)
The Many Questions Raised by the Dual Concept of “Element”
(/isis/citation/CBB802086327/)
Chapter
William B. Jensen;
Carmen J. Giunta;
Vera V. Mainz;
Gregory S. Girolami;
(2021)
The Trouble with Triads
(/isis/citation/CBB736056305/)
Chapter
Gisela Boeck;
Carmen J. Giunta;
Vera V. Mainz;
Gregory S. Girolami;
(2021)
The Periodic Table of the Elements and Lothar Meyer
(/isis/citation/CBB170429677/)
Chapter
Ann E. Robinson;
Carmen J. Giunta;
Vera V. Mainz;
Gregory S. Girolami;
(2021)
Dmitri Mendeleev and the Periodic System: Philosophy, Periodicity, and Predictions
(/isis/citation/CBB516331374/)
Chapter
Simon A. Cotton;
Carmen J. Giunta;
Vera V. Mainz;
Gregory S. Girolami;
(2021)
The Rare Earths, a Challenge to Mendeleev, No Less Today
(/isis/citation/CBB077239037/)
Chapter
Carmen J. Giunta;
Vera V. Mainz;
Julianna Poole-Sawyer;
Gregory S. Girolami;
(2021)
Periodicity in Britain: The Periodic Tables of Odling and Newlands
(/isis/citation/CBB055966538/)
Chapter
Carmen J. Giunta;
Vera V. Mainz;
Gregory S. Girolami;
(2021)
Vis Tellurique of Alexandre-Émile Béguyer de Chancourtois
(/isis/citation/CBB105125958/)
Article
Guillermo Restrepo;
(2022)
Computational History of Chemistry
(/isis/citation/CBB661537090/)
Article
Helge Kragh;
(2019)
Controversial Elements: Priority Disputes and the Discovery of Chemical Elements
(/isis/citation/CBB984827751/)
Chapter
Gregory S. Girolami;
Carmen J. Giunta;
Vera V. Mainz;
(2021)
Gustavus Hinrichs and His Charts of the Elements
(/isis/citation/CBB566269916/)
Be the first to comment!