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Article ID: CBB045320518

Capillary Electrophoresis (CE) and its Basic Principles in Historical Retrospect. Part 3. 1840s –1900ca. The First CE of Ions in 1861. Transference Numbers, Migration Velocity, Conductivity, Mobility. (2022)

Kenndler, Ernst (Author)

Substantia: An International Journal of the History of Chemistry
Volume: 6
Issue: 1
Pages: 77-105

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Chemistry Electrophoresis Electrolysis Physics 19th century Clausius, Rudolf Julius Emmanuel Kohlrausch, Friedrich

Since electrophoresis is a physical phenomenon – it is the movement of dispersed charged particles relative to a liquid under the influence of a spatially uniform electric field - its history is not limited to its use as a separation method. The history of capillary electrophoresis in particular, i.e. electrophoresis in capillary-sized open tubes, therefore does not begin in the 1960s, as is commonly assumed, but already a century earlier, if one refers to its principles.

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