Article ID: CBB000930630

The Origin and Development of the Acidity Function (2009)

unapi

The acidity function is a thermodynamic quantitative measure of acid strength for non-aqueous and concentrated aqueous Brønsted acids, with acid strength being defined as the extent to which the acid protonates a base of known basicity. The acidity function, which was developed, both theoretically and experimentally, by Louis P. Hammett of Columbia University during the 1930s, has proven useful in the area of physical organic chemistry where it has been used to correlate rates of acid-catalyzed reactions and to quantitate the acidity of superacids, acids with protonating abilities greater than pure sulfuric acid. All Brønsted acids can now be compared using a common measure. Karl Popper's seminal idea of theory falsification does not apply here because of the many successful applications of the acidity function. Likewise, Thomas Kuhn's idea of a paradigm shift does not apply here, even though the acidity function concept was revolutionary, because the acidity function is commensurate with classical concepts of acidity. Keywords Louis P. Hammett - Acidity function - Superacid - Hydrogen ion - Proton - Activity - Activity coefficient

...More
Citation URI
https://data.isiscb.org/isis/citation/CBB000930630/

Similar Citations

Article Klaus Ruthenberg; Hasok Chang; (2017)
Acidity: Modes of Characterization and Quantification (/isis/citation/CBB973293015/)

Chapter Rowlinson, Sir John S.; (2014)
James Dewar and the Road to the Liquefaction of Hydrogen (/isis/citation/CBB001500405/)

Book Matthew Shindell; (2019)
The Life and Science of Harold C. Urey (/isis/citation/CBB639943328/)

Article Lafont, Olivier; (2007)
Lavoisier et les radicaux: Radicaux (/isis/citation/CBB000933362/)

Article Seth C. Rasmussen; (2021)
New Insight into the “Fortuitous Error” that Led to the 2000 Nobel Prize in Chemistry (/isis/citation/CBB443189532/)

Book Bosch Giral, Pedro; García de la Banda, Juan Francisco; Pérez Pariente, Joaquin; Toural Quiroga, Manoel; (2010)
Protagonistas de la química en España: Los orígenes de la catálisis (/isis/citation/CBB001220795/)

Article Blai Pié i Valls; Enric Pérez; (2016)
The Historical Role of the Adiabatic Principle in Bohr's Quantum Theory (/isis/citation/CBB403893431/)

Book Gavroglu, Kostas; (2014)
History of Artificial Cold: Scientific, Technological and Cultural Issues (/isis/citation/CBB001500399/)

Article Braun, Robyn; (2011)
Accessory Food Factors: Understanding the Catalytic Function (/isis/citation/CBB001220950/)

Article Kragh, Helge; (2011)
A Controversial Molecule: The Early History of Triatomic Hydrogen (/isis/citation/CBB001230536/)

Article Mawhin, Jean; Ronveaux, André; (2010)
Schrödinger and Dirac Equations for the Hydrogen Atom, and Laguerre Polynomials (/isis/citation/CBB001022003/)

Article Valent, Galliano; (2003)
The Hydrogen Atom in Electric and Magnetic Fields: Pauli's 1926 Article (/isis/citation/CBB000300114/)

Article Jack Cohen; (2021)
The Revolution in Science in America, 1900-1950 (/isis/citation/CBB314257203/)

Authors & Contributors
Blai Pié i Valls
Sztejnberg, Aleksander
Murphy, Mark A.
Rowlinson, Sir John S.
Hernández, Raymundo
Wilholt, Torsten
Concepts
Chemistry
Hydrogen
Physics
Catalysis
Acidity
Theories of heat
Time Periods
20th century, early
20th century
19th century
18th century
21st century
17th century
Places
United States
Russia
France
Scotland
Spain
Comments

Be the first to comment!

{{ comment.created_by.username }} on {{ comment.created_on | date:'medium' }}

Log in or register to comment